Ring-Opening 1,3-Halochalcogenation of Cyclopropane Dicarboxylates
نویسندگان
چکیده
منابع مشابه
Ring-Opening 1,3-Halochalcogenation of Cyclopropane Dicarboxylates
Donor-acceptor cyclopropanes with two geminal carboxylic esters are reacted with chalcogenyl chlorides and bromides to afford ring-opened products bearing the halogen atoms in the 1-position, adjacent to the donor, and the chalcogenyl residue in the 3-position next to the two acceptor groups. A variety of different donors (e.g., aryl, N, and O) are used. The stereospecificity of the reaction is...
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ژورنال
عنوان ژورنال: Organic Letters
سال: 2016
ISSN: 1523-7060,1523-7052
DOI: 10.1021/acs.orglett.6b03375